Jeoloji Münendisliği Dergisi

Genesis of uranium deposits in neogene sedimentary rooks, menderes metamorpMc massif; Turkey

ABSTRACT: Uranium deposits in the Köprübaşı area, Western Turkey occur Im the fluviiitil« sedimentaryrocks, which are uudsuhiin by high grade metamorphlo rocks of the Menderes Massif, These deposits (occur inconglomerates, with abondant eilt and clay matrix and sandstone of coarse clastic Bedlmeötary rocks ofNeagene age. The uranium ore Is present aa matrix Impregnations of uraiiixmi in tabular lenses withinconglomerates and sandstone*. On the basis of their mineralogiical and geochemical oharacteristtcs, they canbe (lividad In to type»; Oxidized and mvDxldlzed, Oxidized deposit can be subdivided In to jarosite-waylanolte richand ilmenite-magiieti`te subtypes`, both of which occur near exposures of uetamorphio basement rocks.Uranium in the lunenlte-magnettte rich subtype is disseminated unUiwmly throughout the sand matrix ofconglomerate whereas it is found in the jarosijte-waylandlte miatture in the jarosrfte-waylandite subtype. Theunoxfdlzed second type contains outhigenlo pyrite and siderite. Vranium in this type is also disseminatedthroughout the clay matrix of fflhe sandstone body. Ore grade uranium concentrations In the unoxWlzed deposit is confined to pyrite-rioh zones, whereas onlylow grade miiicriJi/.ution loeeurs In Blderlte-rlol| zones. Authlgenfcally formed pyrite during and after diiagenesis, which was important la establishtag a favourable geoehemloal environment, was oxidized by movinggroiHufwater resulting In eonsumptton of oxygen inpyriite-rich zones, with consequent formation of aulfiteby pyrtte breakdown. Sulfite, subsequently, disproportionate^ in to HS and SOr The HS generated by thisprocess is believed to have been the major reducing ageng during the formation of this deposit. Althoughthe Jarosite-waylandite-assooiated uraium deposits occur m the oxidized ground, they were apparently derivedfrom oxidation of other unoxidlzed bodies. All the deposits, therefore, are epigeneMo in origin, formed byprecipitation *of uranium by groundwater solution» that moved through host rook. The basement metamorphlcrooks are believed to have been the major source of uranium